Experimental determination of the long-time behavior in reversible binary chemical reactions

Dan Huppert, Sinay Y. Goldberg, Asnat Masad, Noam Agmon

Research output: Contribution to journalArticlepeer-review

Abstract

A new asymptotic behavior of reversible pseudo first-order binary chemical reactions is revealed by time-resolved fluorescence measurements of excited-state proton transfer. The asymptotic behavior is a power-law rather than the exponential decay expected from the chemical rate equations. Unlike the conclusion from mean-field approximations, the power seems to increase with concentration.

Original languageEnglish
Pages (from-to)3932-3935
Number of pages4
JournalPhysical Review Letters
Volume68
Issue number26
DOIs
StatePublished - 1992

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