Expanding possibilities for solid-phase crystallization by exsolving tunable Pd-NiO core-shell nanostructures

Mariana Buharon; Sarika Singh; Eswaravara P. Komarala; Brian A. Rosen

doi:10.1039/c8ce01294f

Expanding possibilities for solid-phase crystallization by exsolving tunable Pd-NiO core-shell nanostructures

Mariana Buharon, Sarika Singh, Eswaravara P. Komarala, Brian A. Rosen^*

^*Corresponding author for this work

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The major drawbacks of solid-phase crystallization as a means of synthesizing catalysts are the lack of heterogeneous structural diversity and the comparatively low metal dispersion it affords. By leveraging differences in reducibility and composition in the parent perovskite B-site, highly disperse Pd-NiO core-shell nanoparticles with a tunable shell thickness can be grown.

Original language	English
Pages (from-to)	6372-6376
Number of pages	5
Journal	CrystEngComm
Volume	20
Issue number	41
DOIs	https://doi.org/10.1039/c8ce01294f
State	Published - 2018

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title = "Expanding possibilities for solid-phase crystallization by exsolving tunable Pd-NiO core-shell nanostructures",

abstract = "The major drawbacks of solid-phase crystallization as a means of synthesizing catalysts are the lack of heterogeneous structural diversity and the comparatively low metal dispersion it affords. By leveraging differences in reducibility and composition in the parent perovskite B-site, highly disperse Pd-NiO core-shell nanoparticles with a tunable shell thickness can be grown.",

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AU - Rosen, Brian A.

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AB - The major drawbacks of solid-phase crystallization as a means of synthesizing catalysts are the lack of heterogeneous structural diversity and the comparatively low metal dispersion it affords. By leveraging differences in reducibility and composition in the parent perovskite B-site, highly disperse Pd-NiO core-shell nanoparticles with a tunable shell thickness can be grown.

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Expanding possibilities for solid-phase crystallization by exsolving tunable Pd-NiO core-shell nanostructures

Abstract

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