Evidence for metal-ligand cooperation in a Pd-PNF pincer-catalyzed cross-coupling

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Abstract

The first Pd-pincer complex bearing a halogen (fluorine) arm has been prepared via the base-assisted dearomatization of a phosphine-quinoline (P∼N) ligand. This dearomatization is reversible and has been used to facilitate catalytic Sonogashira-type cross-coupling that, contrary to the typical mechanistic approach, is based on a metal-ligand cooperation mode.

Original languageEnglish
Pages (from-to)967-970
Number of pages4
JournalJournal of the American Chemical Society
Volume135
Issue number3
DOIs
StatePublished - 23 Jan 2013

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