Epoxidation of Olefins with Elemental Fluorine in Water/Acetonitrile Mixtures

Shlomo Rozen; Michael Brand

doi:10.1002/anie.198605541

Epoxidation of Olefins with Elemental Fluorine in Water/Acetonitrile Mixtures

Shlomo Rozen^*, Michael Brand

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

Not fluorinated compounds but rather epoxides are formed in good yields from alkenes with the reagent F₂/MeCN/H₂O. Both alkenes with a terminal double bond, which are especially sensitive to oxidation, and enones react smoothly.

Original language	English
Pages (from-to)	554-555
Number of pages	2
Journal	Angewandte Chemie - International Edition
Volume	25
Issue number	6
DOIs	https://doi.org/10.1002/anie.198605541
State	Published - Jun 1986

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title = "Epoxidation of Olefins with Elemental Fluorine in Water/Acetonitrile Mixtures",

abstract = "Not fluorinated compounds but rather epoxides are formed in good yields from alkenes with the reagent F2/MeCN/H2O. Both alkenes with a terminal double bond, which are especially sensitive to oxidation, and enones react smoothly.",

author = "Shlomo Rozen and Michael Brand",

year = "1986",

month = jun,

doi = "10.1002/anie.198605541",

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AB - Not fluorinated compounds but rather epoxides are formed in good yields from alkenes with the reagent F2/MeCN/H2O. Both alkenes with a terminal double bond, which are especially sensitive to oxidation, and enones react smoothly.

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JO - Angewandte Chemie - International Edition

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Epoxidation of Olefins with Elemental Fluorine in Water/Acetonitrile Mixtures

Abstract

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