Entropic competition between knots and slip-links

Roya Zandi*, Yacov Kantor, Mehran Kardar

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Using canonical Monte Carlo simulations, we introduce a new numerical procedure for comparing the entropie exponents of polymers with different constraints and/or topologies. Setting up competitions between polymer segments which can exchange monomers according to their free energies, we obtain the universal exponents of partition functions, independently of any knowledge of the non-universal part. The method is successfully tested for closed polymer loops decorated with sliding rings. We also investigate the entropic exponents of loops with a fixed knot type, in which case we are limited by strong finite-size effects.

Original languageEnglish
Pages (from-to)6-15
Number of pages10
JournalARI Bulletin of the Istanbul Technical University
Volume53
Issue number1
StatePublished - 2003

Keywords

  • Critical exponents
  • Knots
  • Polymers
  • Rings
  • Self-avoiding walks
  • Topological entanglement

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