Enhancing the Sensitivity of Chemical Sensors for Chlorinated Hydrocarbons in Water by the Use of Tapered Silver Halide Fibers and Tunable Diode Lasers

Roman Göbel*, Rudolf Krska, Robert Kellner, Joachim Kastner, Armin Lambrecht, Maurus Tacke, Abraham Katzir

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

37 Scopus citations

Abstract

Tapered silver halide fibers were used for the first time for high-sensitivity fiber evanescent wave spectroscopic (FEWS) measurements of chlorinated hydrocarbons (CHCs) in water at trace level. The sensor arrangement consisted of a tunable diode laser (TDL) source, a polymer-coated and tapered silver halide fiber, and a direct fiber/mercury cadmium telluride (MCT) detector coupling. A minimum detection limit of 50 μg L−1 was achieved by using a polyisobutylene-coated fiber with a 1:4 tapering ratio. The sensor response is in the minute range and shows reversible analyte enrichment.

Original languageEnglish
Pages (from-to)1174-1177
Number of pages4
JournalApplied Spectroscopy
Volume49
Issue number8
DOIs
StatePublished - Aug 1995

Keywords

  • Chemical sensor
  • Chlorinated hydrocarbons
  • Fiber evanescent wave spectroscopy (FEWS)
  • Tapered fibers
  • Tunable diode laser (TDL)

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