Enhancement of Energy Storage and Photoresponse Properties of Folic Acid-Polyaniline Hybrid Hydrogel by in Situ Growth of Ag Nanoparticles

Electrically conductive hydrogels are a fascinating class of materials that exhibit multifarious applications such as photoresponse, energy storage, etc., and the three-dimensional micro- and nanofibrillar structures of the gels are the key to those applications. Herein, we have synthesized a hybrid hydrogel based on folic acid (F) and polyaniline (PANI) in which F acts as a supramolecular cross-linker of PANI chains. The gels are mechanically robust and are characterized by field-emission scanning electron microscopy, transmission electron microscopy, and spectroscopic, rheological, and universal testing measurements. The hybrid xerogel exhibit a BET surface area 238 m² g-¹, conductivity of 0.04 S/cm, specific capacitance of 295 F/g at a current density of 1A/g, and photocurrent of ∼2 mA under white-light illumination. Silver nanoparticles (AgNPs) are in situ grown to elegantly improve the conductivity, energy storage, and photoresponse capability of the gels. The formation of AgNPs drastically improves the specific capacitances up to 646 F/g (at current density 1A/g), excellent rate capability (403 F/g at 20 A/g), and stable cycling performance with a retention ratio of 74% after 5000 cycles. The AgNPs embedded gel exhibits dramatic enhancement of photocurrent to 56 mA, and its time-dependent photoillumination corroborates faster rise and decay of current compared to those of folic acid-polyaniline hydrogel.