Energy, Work, Entropy, and Heat Balance in Marcus Molecular Junctions

Natalya A. Zimbovskaya, Abraham Nitzan*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

We present a consistent theory of energy balance and conversion in a single-molecule junction with strong interactions between electrons on the molecular linker (dot) and phonons in the nuclear environment where the Marcus-Type electron hopping processes predominate in the electron transport. It is shown that the environmental reorganization and relaxation that accompany electron hopping energy exchange between the electrodes and the nuclear (molecular and solvent) environment may bring a moderate local cooling of the latter in biased systems. The effect of a periodically driven dot level on the heat transport and power generated in the system is analyzed, and energy conservation is demonstrated both within and beyond the quasistatic regime. Finally, a simple model of atomic scale engine based on a Marcus single-molecule junction with a driven electron level is suggested and discussed.

Original languageEnglish
Pages (from-to)2632-2642
Number of pages11
JournalJournal of Physical Chemistry B
Volume124
Issue number13
DOIs
StatePublished - 2 Apr 2020

Funding

FundersFunder number
National Science FoundationCHE1665291, DMR-PREM 1523463, 1665291
University of Pennsylvania
Deutsche ForschungsgemeinschaftTH 820/11-1
United States-Israel Binational Science Foundation
Tel Aviv University

    Fingerprint

    Dive into the research topics of 'Energy, Work, Entropy, and Heat Balance in Marcus Molecular Junctions'. Together they form a unique fingerprint.

    Cite this