Encapsulated or not encapsulated? mapping alcohol sites in hexameric capsules of resorcin[4]arenes in solution by diffusion NMR spectroscopy

Sarit Slovak; Liat Avram; Yoram Cohen

doi:10.1002/anie.200904952

Encapsulated or not encapsulated? mapping alcohol sites in hexameric capsules of resorcin[4]arenes in solution by diffusion NMR spectroscopy

Sarit Slovak^*
, Liat Avram
, Yoram Cohen

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

"Chemical Equation Presented" Knock, knock! Despite the similar high-field ¹H NMR spectra of different alcohols in the presence of hexameric capsules of resorcin[4]arenes, diffusion NMR spectroscopy showed that only some of these alcohols are truly encapsulated in the hexameric capsules, whereas other alcohols are part of the hexameric structure of the capsules (see schematic representation; R=C₁₁H₂₃).

Original language	English
Pages (from-to)	428-431
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	2
DOIs	https://doi.org/10.1002/anie.200904952
State	Published - 8 Jan 2010

Keywords

Alcohols
Diffusion nmr spectroscopy
Hostguest systems
Molecular capsules
Supramolecular chemistry

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10.1002/anie.200904952

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abstract = "{"}Chemical Equation Presented{"} Knock, knock! Despite the similar high-field 1H NMR spectra of different alcohols in the presence of hexameric capsules of resorcin[4]arenes, diffusion NMR spectroscopy showed that only some of these alcohols are truly encapsulated in the hexameric capsules, whereas other alcohols are part of the hexameric structure of the capsules (see schematic representation; R=C11H23).",

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author = "Sarit Slovak and Liat Avram and Yoram Cohen",

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AU - Cohen, Yoram

PY - 2010/1/8

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N2 - "Chemical Equation Presented" Knock, knock! Despite the similar high-field 1H NMR spectra of different alcohols in the presence of hexameric capsules of resorcin[4]arenes, diffusion NMR spectroscopy showed that only some of these alcohols are truly encapsulated in the hexameric capsules, whereas other alcohols are part of the hexameric structure of the capsules (see schematic representation; R=C11H23).

AB - "Chemical Equation Presented" Knock, knock! Despite the similar high-field 1H NMR spectra of different alcohols in the presence of hexameric capsules of resorcin[4]arenes, diffusion NMR spectroscopy showed that only some of these alcohols are truly encapsulated in the hexameric capsules, whereas other alcohols are part of the hexameric structure of the capsules (see schematic representation; R=C11H23).

KW - Alcohols

KW - Diffusion nmr spectroscopy

KW - Hostguest systems

KW - Molecular capsules

KW - Supramolecular chemistry

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DO - 10.1002/anie.200904952

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JF - Angewandte Chemie - International Edition

IS - 2

ER -

Encapsulated or not encapsulated? mapping alcohol sites in hexameric capsules of resorcin[4]arenes in solution by diffusion NMR spectroscopy

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Keywords

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