TY - JOUR
T1 - Encapsulated or not encapsulated? mapping alcohol sites in hexameric capsules of resorcin[4]arenes in solution by diffusion NMR spectroscopy
AU - Slovak, Sarit
AU - Avram, Liat
AU - Cohen, Yoram
PY - 2010/1/8
Y1 - 2010/1/8
N2 - "Chemical Equation Presented" Knock, knock! Despite the similar high-field 1H NMR spectra of different alcohols in the presence of hexameric capsules of resorcin[4]arenes, diffusion NMR spectroscopy showed that only some of these alcohols are truly encapsulated in the hexameric capsules, whereas other alcohols are part of the hexameric structure of the capsules (see schematic representation; R=C11H23).
AB - "Chemical Equation Presented" Knock, knock! Despite the similar high-field 1H NMR spectra of different alcohols in the presence of hexameric capsules of resorcin[4]arenes, diffusion NMR spectroscopy showed that only some of these alcohols are truly encapsulated in the hexameric capsules, whereas other alcohols are part of the hexameric structure of the capsules (see schematic representation; R=C11H23).
KW - Alcohols
KW - Diffusion nmr spectroscopy
KW - Hostguest systems
KW - Molecular capsules
KW - Supramolecular chemistry
UR - http://www.scopus.com/inward/record.url?scp=73349103791&partnerID=8YFLogxK
U2 - 10.1002/anie.200904952
DO - 10.1002/anie.200904952
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C2 - 19967684
AN - SCOPUS:73349103791
SN - 1433-7851
VL - 49
SP - 428
EP - 431
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 2
ER -