TY - JOUR
T1 - Emission spectrum of CdCH3
AU - Penner, Abraham
AU - Amirav, Aviv
AU - Bersohn, Richard
N1 - Funding Information:
This research was supported by the fund for basic research administered by the Israel Academy of Sciences and Humanities (A.4), by the US National Science Foundation (RB ) and by the USA-Israel Binational Science Foundation, Grant No. 88-00 198 (AA and RB).
PY - 1991/1/11
Y1 - 1991/1/11
N2 - Laser excitation at 206-232 nm of a supersonic free jet of Cd(CH3)2 produced an emission due to one-photon absorption from vibrationally cold à CdCH3. The 0-0 line was at 444.1 nm and ground-state vibrational frequencies of 345 cm-1 (CdCH3 stretch) and 998 cm-1 (CH3 umbrella mode) were measured. Much stronger emissions caused by multiphoton absorption were seen at the atomic lines of Cd 3P1 (326.1 nm) and Cd 1P (228.8 nm), and the A→X transition of CH.
AB - Laser excitation at 206-232 nm of a supersonic free jet of Cd(CH3)2 produced an emission due to one-photon absorption from vibrationally cold à CdCH3. The 0-0 line was at 444.1 nm and ground-state vibrational frequencies of 345 cm-1 (CdCH3 stretch) and 998 cm-1 (CH3 umbrella mode) were measured. Much stronger emissions caused by multiphoton absorption were seen at the atomic lines of Cd 3P1 (326.1 nm) and Cd 1P (228.8 nm), and the A→X transition of CH.
UR - http://www.scopus.com/inward/record.url?scp=0343303236&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(91)90146-Z
DO - 10.1016/0009-2614(91)90146-Z
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AN - SCOPUS:0343303236
SN - 0009-2614
VL - 176
SP - 147
EP - 151
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 2
ER -