TY - JOUR
T1 - Effect of ligand isomerism on the formation of magnesium-based coordination networks
AU - Liu, Tingzhi
AU - Luo, Daibing
AU - Xu, Dingguo
AU - Wang, Kangcai
AU - Lin, Zhien
N1 - Publisher Copyright:
© 2014 Elsevier B.V. All rights reserved.
PY - 2014/10
Y1 - 2014/10
N2 - Three magnesium-based coordination polymers, formulated as Mg(3,4-pyb)2 (1), Mg(4,3-pyb)2 (2), and Mg2.5(4,4-pyb)2(HCOO)2(OH) (3), have been synthesized under solvothermal conditions, where 3,4-pyb = 3-(pyridin-4-yl)benzoate, 4,3-pyb = 4-(pyridin-3-yl)benzoate, and 4,4-pyb = 4-(pyridin-4-yl)benzoate. Compounds 1 and 2 have (3,6)-connected frameworks with an anatase topology. Compound 3 has a (3,8)-connected framework with an unusual tfz-d topology by regarding Mg5(HCOO)4(OH)2 clusters as 8-connected nodes and bridging 4,4-pyb ligands as 3-connected nodes.
AB - Three magnesium-based coordination polymers, formulated as Mg(3,4-pyb)2 (1), Mg(4,3-pyb)2 (2), and Mg2.5(4,4-pyb)2(HCOO)2(OH) (3), have been synthesized under solvothermal conditions, where 3,4-pyb = 3-(pyridin-4-yl)benzoate, 4,3-pyb = 4-(pyridin-3-yl)benzoate, and 4,4-pyb = 4-(pyridin-4-yl)benzoate. Compounds 1 and 2 have (3,6)-connected frameworks with an anatase topology. Compound 3 has a (3,8)-connected framework with an unusual tfz-d topology by regarding Mg5(HCOO)4(OH)2 clusters as 8-connected nodes and bridging 4,4-pyb ligands as 3-connected nodes.
KW - Coordination polymer
KW - Crystal structure
KW - Magnesium
KW - Solvothermal synthesis
KW - Topological analysis
UR - http://www.scopus.com/inward/record.url?scp=84907842811&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2014.08.034
DO - 10.1016/j.inoche.2014.08.034
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AN - SCOPUS:84907842811
SN - 1387-7003
VL - 48
SP - 136
EP - 139
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
ER -