Effect of diffusion layer structure on the electroreflectance of metals

M. I. Urbakh; A. B. Ershler

doi:10.1016/0013-4686(84)87161-3

Effect of diffusion layer structure on the electroreflectance of metals

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Abstract

The component of electroreflectance (ER) of metals due to the modulation of the diffusion layer characteristics has been investigated. It has been shown that the contribution of this effect to the total ER signal is greatest at large incidence angles. The diffusion contribution to ER is particularly great near the desorption peak of the organic substance. Analytical expressions for the diffusion component of ER as a function of the incidence angle and potential drop modulation frequency have been obtained. The theoretical conclusions have been verified experimentally.

Original language	English
Pages (from-to)	1101-1106
Number of pages	6
Journal	Electrochimica Acta
Volume	29
Issue number	8
DOIs	https://doi.org/10.1016/0013-4686(84)87161-3
State	Published - Aug 1984
Externally published	Yes

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10.1016/0013-4686(84)87161-3

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title = "Effect of diffusion layer structure on the electroreflectance of metals",

abstract = "The component of electroreflectance (ER) of metals due to the modulation of the diffusion layer characteristics has been investigated. It has been shown that the contribution of this effect to the total ER signal is greatest at large incidence angles. The diffusion contribution to ER is particularly great near the desorption peak of the organic substance. Analytical expressions for the diffusion component of ER as a function of the incidence angle and potential drop modulation frequency have been obtained. The theoretical conclusions have been verified experimentally.",

author = "Urbakh, {M. I.} and Ershler, {A. B.}",

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AU - Urbakh, M. I.

AU - Ershler, A. B.

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N2 - The component of electroreflectance (ER) of metals due to the modulation of the diffusion layer characteristics has been investigated. It has been shown that the contribution of this effect to the total ER signal is greatest at large incidence angles. The diffusion contribution to ER is particularly great near the desorption peak of the organic substance. Analytical expressions for the diffusion component of ER as a function of the incidence angle and potential drop modulation frequency have been obtained. The theoretical conclusions have been verified experimentally.

AB - The component of electroreflectance (ER) of metals due to the modulation of the diffusion layer characteristics has been investigated. It has been shown that the contribution of this effect to the total ER signal is greatest at large incidence angles. The diffusion contribution to ER is particularly great near the desorption peak of the organic substance. Analytical expressions for the diffusion component of ER as a function of the incidence angle and potential drop modulation frequency have been obtained. The theoretical conclusions have been verified experimentally.

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JO - Electrochimica Acta

JF - Electrochimica Acta

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ER -

Effect of diffusion layer structure on the electroreflectance of metals

Abstract

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