Abstract
(Matrix presented) Following the discovery that meso-substituted corroles are formed in solvent-free condensation of pyrrole with aldehydes, we demonstrate that a small variation in the methodology is suitable for facile synthesis of cobalt(III) corrole and hexaphyrin. These compounds, as well as three noncyclic products, were fully characterized by spectroscopy and X-ray crystallography.
Original language | English |
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Pages (from-to) | 1241-1244 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 5 |
Issue number | 8 |
DOIs | |
State | Published - 17 Apr 2003 |