Easy preparation of cobalt corrole and hexaphyrin and isolation of new oligopyrroles in the solvent-free condensation of pyrrole with pentafluorobenzaldehyde

Liliya Simkhovich; Israel Goldberg; Zeev Gross

doi:10.1021/ol0341142

Easy preparation of cobalt corrole and hexaphyrin and isolation of new oligopyrroles in the solvent-free condensation of pyrrole with pentafluorobenzaldehyde

Liliya Simkhovich, Israel Goldberg, Zeev Gross^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(Matrix presented) Following the discovery that meso-substituted corroles are formed in solvent-free condensation of pyrrole with aldehydes, we demonstrate that a small variation in the methodology is suitable for facile synthesis of cobalt(III) corrole and hexaphyrin. These compounds, as well as three noncyclic products, were fully characterized by spectroscopy and X-ray crystallography.

Original language	English
Pages (from-to)	1241-1244
Number of pages	4
Journal	Organic Letters
Volume	5
Issue number	8
DOIs	https://doi.org/10.1021/ol0341142
State	Published - 17 Apr 2003

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10.1021/ol0341142

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abstract = "(Matrix presented) Following the discovery that meso-substituted corroles are formed in solvent-free condensation of pyrrole with aldehydes, we demonstrate that a small variation in the methodology is suitable for facile synthesis of cobalt(III) corrole and hexaphyrin. These compounds, as well as three noncyclic products, were fully characterized by spectroscopy and X-ray crystallography.",

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AU - Simkhovich, Liliya

AU - Goldberg, Israel

AU - Gross, Zeev

PY - 2003/4/17

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N2 - (Matrix presented) Following the discovery that meso-substituted corroles are formed in solvent-free condensation of pyrrole with aldehydes, we demonstrate that a small variation in the methodology is suitable for facile synthesis of cobalt(III) corrole and hexaphyrin. These compounds, as well as three noncyclic products, were fully characterized by spectroscopy and X-ray crystallography.

AB - (Matrix presented) Following the discovery that meso-substituted corroles are formed in solvent-free condensation of pyrrole with aldehydes, we demonstrate that a small variation in the methodology is suitable for facile synthesis of cobalt(III) corrole and hexaphyrin. These compounds, as well as three noncyclic products, were fully characterized by spectroscopy and X-ray crystallography.

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Easy preparation of cobalt corrole and hexaphyrin and isolation of new oligopyrroles in the solvent-free condensation of pyrrole with pentafluorobenzaldehyde

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