Dithiodiolate Ligands: Group 4 complexes and application in lactide polymerization

Ekaterina Sergeeva, Jacob Kopilov, Israel Goldberg, Moshe Kol

Research output: Contribution to journalArticlepeer-review

Abstract

Dithiodiolate ligands were synthesized by reacting 1,2-ethanedithiol or 1,2-benzenedithiol with 2,2-bis(trifluoromethyl)oxirane, led selectively to mononuclear octahedral group 4 complexes of the type [{OSSO}M(OR)2], which features C2 symmetry and fluxional behavior, and were highly active in the ring-opening polymerization of rac- and l-lactide.

Original languageEnglish
Pages (from-to)3977-3979
Number of pages3
JournalInorganic Chemistry
Volume49
Issue number9
DOIs
StatePublished - 3 May 2010

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