Abstract
The nature of the pair interaction between dipoles embedded in a liquid in the vicinity of a nonmetallic interface is investigated in the continuum limit. It is shown that the dipole-dipole interaction can be significantly modified in the presence of a boundary in liquids characterized by a nonlocal dielectric function or in liquids whose dielectric properties change due to geometrical restrictions. Different limits are studied and relationships to experimental observables are discussed.
Original language | English |
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Pages (from-to) | 3344-3349 |
Number of pages | 6 |
Journal | Journal of Physical Chemistry |
Volume | 97 |
Issue number | 13 |
DOIs | |
State | Published - 1993 |