TY - JOUR
T1 - (Dimethylacetamide)(tetraphenylporphyrinato)-zinc(II)
AU - Lipstman, Sophia
AU - Muniappan, Sankar
AU - Goldberg, Israel
PY - 2006/9
Y1 - 2006/9
N2 - The title compound, [Zn(C44H28N4)(C 4H9NO)], represents a five-coordinate zinc-porphyrin complex with N,N′-dimethylacetamide as an axial ligand of typical domed geometry. The latter reveals a twofold orientational disorder. The crystal structure is characterized by a layered organization of the porphyrin species. In a given layer, all axial ligands are oriented in the same direction, while neighboring layers are related to each other by crystallographic inversion.
AB - The title compound, [Zn(C44H28N4)(C 4H9NO)], represents a five-coordinate zinc-porphyrin complex with N,N′-dimethylacetamide as an axial ligand of typical domed geometry. The latter reveals a twofold orientational disorder. The crystal structure is characterized by a layered organization of the porphyrin species. In a given layer, all axial ligands are oriented in the same direction, while neighboring layers are related to each other by crystallographic inversion.
UR - http://www.scopus.com/inward/record.url?scp=33748550988&partnerID=8YFLogxK
U2 - 10.1107/S1600536806034064
DO - 10.1107/S1600536806034064
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AN - SCOPUS:33748550988
SN - 1600-5368
VL - 62
SP - m2330-m2332
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 9
ER -