Dimer ring-closing metathesis

Charles E. Diesendruck; Amos Ben-Asuly; Israel Goldberg; N. Gabriel Lemcoff

Dimer ring-closing metathesis

Charles E. Diesendruck, Amos Ben-Asuly, Israel Goldberg, N. Gabriel Lemcoff

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Homodinuclear ruthenium catalysts with rigid spacers were used in the discovery of a new olefin metathesis reaction: Dimer Ring Closing Metathesis (DRCM). The development of DRCM is commented and the synthesis of a new di-ruthenium complex is presented. The new complex was shown to be active in olefin metathesis, but it was not selective for DRCM. The future perspectives for the exciting DRC reaction are also discussed.

Original language	English
Pages (from-to)	15-18
Number of pages	4
Journal	Chimica Oggi
Volume	28
Issue number	3
State	Published - May 2010

Keywords

Carbene ligands
Cyclization
Dimer ring-closing
Metathesis
Ruthenium

Cite this

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AU - Diesendruck, Charles E.

AU - Ben-Asuly, Amos

AU - Goldberg, Israel

AU - Lemcoff, N. Gabriel

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N2 - Homodinuclear ruthenium catalysts with rigid spacers were used in the discovery of a new olefin metathesis reaction: Dimer Ring Closing Metathesis (DRCM). The development of DRCM is commented and the synthesis of a new di-ruthenium complex is presented. The new complex was shown to be active in olefin metathesis, but it was not selective for DRCM. The future perspectives for the exciting DRC reaction are also discussed.

AB - Homodinuclear ruthenium catalysts with rigid spacers were used in the discovery of a new olefin metathesis reaction: Dimer Ring Closing Metathesis (DRCM). The development of DRCM is commented and the synthesis of a new di-ruthenium complex is presented. The new complex was shown to be active in olefin metathesis, but it was not selective for DRCM. The future perspectives for the exciting DRC reaction are also discussed.

KW - Carbene ligands

KW - Cyclization

KW - Dimer ring-closing

KW - Metathesis

KW - Ruthenium

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JF - Chimica Oggi

SN - 0392-839X

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Dimer ring-closing metathesis

Abstract

Keywords

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