Dibenzoeilatin: A novel ligand exhibiting remarkable complementary π–π stacking interactions

Sheba D. Bergman; Dvora Reshef; Stanislav Groysman; Israel Goldberg; Moshe Kol

doi:10.1039/b206058b

Dibenzoeilatin: A novel ligand exhibiting remarkable complementary π–π stacking interactions

Sheba D. Bergman, Dvora Reshef, Stanislav Groysman, Israel Goldberg, Moshe Kol^*

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The complex [Ru(bpy)₂(dbneil)][PF₆]₂ forms discrete dimers in solution held by strong π–π stacking interactions via its distorted dibenzoeilatin ligand, indicating that planarity is not an obligatory requirement for achieving strong π-stacking, as long as complementarity between the stacking moieties can be achieved.

Original language	English
Pages (from-to)	2374-2375
Number of pages	2
Journal	Chemical Communications
Volume	2
Issue number	20
DOIs	https://doi.org/10.1039/b206058b
State	Published - 2002

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title = "Dibenzoeilatin: A novel ligand exhibiting remarkable complementary π–π stacking interactions",

abstract = "The complex [Ru(bpy)2(dbneil)][PF6]2 forms discrete dimers in solution held by strong π–π stacking interactions via its distorted dibenzoeilatin ligand, indicating that planarity is not an obligatory requirement for achieving strong π-stacking, as long as complementarity between the stacking moieties can be achieved.",

author = "Bergman, {Sheba D.} and Dvora Reshef and Stanislav Groysman and Israel Goldberg and Moshe Kol",

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doi = "10.1039/b206058b",

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AU - Bergman, Sheba D.

AU - Reshef, Dvora

AU - Groysman, Stanislav

AU - Goldberg, Israel

AU - Kol, Moshe

PY - 2002

Y1 - 2002

N2 - The complex [Ru(bpy)2(dbneil)][PF6]2 forms discrete dimers in solution held by strong π–π stacking interactions via its distorted dibenzoeilatin ligand, indicating that planarity is not an obligatory requirement for achieving strong π-stacking, as long as complementarity between the stacking moieties can be achieved.

AB - The complex [Ru(bpy)2(dbneil)][PF6]2 forms discrete dimers in solution held by strong π–π stacking interactions via its distorted dibenzoeilatin ligand, indicating that planarity is not an obligatory requirement for achieving strong π-stacking, as long as complementarity between the stacking moieties can be achieved.

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VL - 2

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JO - Chemical Communications

JF - Chemical Communications

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Dibenzoeilatin: A novel ligand exhibiting remarkable complementary π–π stacking interactions

Abstract

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