Diastereomerically-specific zirconium complexes of chiral salan ligands: Isospecific polymerization of 1-hexene and 4-methyl-1-pentene and cyclopolymerization of 1,5-hexadiene

Adi Yeori; Israel Goldberg; Michael Shuster; Moshe Kol

doi:10.1021/ja0647654

Diastereomerically-specific zirconium complexes of chiral salan ligands: Isospecific polymerization of 1-hexene and 4-methyl-1-pentene and cyclopolymerization of 1,5-hexadiene

Adi Yeori, Israel Goldberg, Michael Shuster, Moshe Kol^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Chiral Salan ligands were found to wrap in a highly diastereoselective manner around zirconium leading to C2-symmetric complexes of predetermined chirality at the metal. These complexes led to active polymerization of higher olefins, their activity and isospecific induction depending on the nature of the phenolate substituents.

Original language	English
Pages (from-to)	13062-13063
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	40
DOIs	https://doi.org/10.1021/ja0647654
State	Published - 11 Oct 2006

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title = "Diastereomerically-specific zirconium complexes of chiral salan ligands: Isospecific polymerization of 1-hexene and 4-methyl-1-pentene and cyclopolymerization of 1,5-hexadiene",

abstract = "Chiral Salan ligands were found to wrap in a highly diastereoselective manner around zirconium leading to C2-symmetric complexes of predetermined chirality at the metal. These complexes led to active polymerization of higher olefins, their activity and isospecific induction depending on the nature of the phenolate substituents.",

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Diastereomerically-specific zirconium complexes of chiral salan ligands: Isospecific polymerization of 1-hexene and 4-methyl-1-pentene and cyclopolymerization of 1,5-hexadiene. / Yeori, Adi; Goldberg, Israel; Shuster, Michael et al.
In: Journal of the American Chemical Society, Vol. 128, No. 40, 11.10.2006, p. 13062-13063.

Research output: Contribution to journal › Article › peer-review

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T1 - Diastereomerically-specific zirconium complexes of chiral salan ligands

T2 - Isospecific polymerization of 1-hexene and 4-methyl-1-pentene and cyclopolymerization of 1,5-hexadiene

AU - Yeori, Adi

AU - Goldberg, Israel

AU - Shuster, Michael

AU - Kol, Moshe

PY - 2006/10/11

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AB - Chiral Salan ligands were found to wrap in a highly diastereoselective manner around zirconium leading to C2-symmetric complexes of predetermined chirality at the metal. These complexes led to active polymerization of higher olefins, their activity and isospecific induction depending on the nature of the phenolate substituents.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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Diastereomerically-specific zirconium complexes of chiral salan ligands: Isospecific polymerization of 1-hexene and 4-methyl-1-pentene and cyclopolymerization of 1,5-hexadiene

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