Cycloadditions of 3,4-dimethyl-1-thio-1-phenyl phosphole

Y. Kashman*, I. Wagenstein, A. Rudi

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Phosphole sulfide 1 undergoes cycloaddition to give a new 15-phosphasteroid. The 13C-NMR and 2JPC-coupling constants of several compounds prepared similarly are discussed, permitting structure assignment to one of the 7-phosphabicyclo[2.2.1]heptane adduct 5. Thiophosgene reacts with the PS moiety of 1, giving 12 after hydrolysis, through a PS to PO transformation coupled in case of 1 with a proton migration.

Original languageEnglish
Pages (from-to)2427-2431
Number of pages5
JournalTetrahedron
Volume32
Issue number20
DOIs
StatePublished - 1976

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