Cyclic Voltammetry In Solutions Of Aluminum Bromide And Kbr In Aromatic Hydrocarbons Iii. The Behavior Of Ag And Cu

M. Elam; E. Peled; E. Gileadi

doi:10.1149/1.2116019

Cyclic Voltammetry In Solutions Of Aluminum Bromide And Kbr In Aromatic Hydrocarbons Iii. The Behavior Of Ag And Cu

M. Elam, E. Peled, E. Gileadi

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The electrochemical behavior of AgBr and CuBr has been studied in a solution consisting of 0.80M KBr and 1.0M Al₂Br₆ in ethylbenzene. A significant crystallization overpotential is observed for Cu on Pt, while silver exhibits only a marginally small crystallization overpotential. Measurements of the diffusion coefficients by different methods and comparison with earlier results yield values in the range of (1.1-2.9) x 10^-6cm²/s (corresponding to Stokes radii of 9-4Å), except for Cu, which yields a value of (10–21) x 10^-6cm²/s. These high apparent values are probably due to catalytic decomposition of the solvent caused by the presence of cuprous ions. The relatively high value for the diffusion coefficient of mercuric ions in toluene reported in an earlier publication is probably due to the same effect.

Original language	English
Pages (from-to)	2058-2062
Number of pages	5
Journal	Journal of the Electrochemical Society
Volume	131
Issue number	9
DOIs	https://doi.org/10.1149/1.2116019
State	Published - Sep 1984

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1149/1.2116019

Cite this

@article{dcaea985186346a386fba740acfbd59b,

title = "Cyclic Voltammetry In Solutions Of Aluminum Bromide And Kbr In Aromatic Hydrocarbons Iii. The Behavior Of Ag And Cu",

abstract = "The electrochemical behavior of AgBr and CuBr has been studied in a solution consisting of 0.80M KBr and 1.0M Al2Br6 in ethylbenzene. A significant crystallization overpotential is observed for Cu on Pt, while silver exhibits only a marginally small crystallization overpotential. Measurements of the diffusion coefficients by different methods and comparison with earlier results yield values in the range of (1.1-2.9) x 10-6cm2/s (corresponding to Stokes radii of 9-4{\AA}), except for Cu, which yields a value of (10–21) x 10-6cm2/s. These high apparent values are probably due to catalytic decomposition of the solvent caused by the presence of cuprous ions. The relatively high value for the diffusion coefficient of mercuric ions in toluene reported in an earlier publication is probably due to the same effect.",

author = "M. Elam and E. Peled and E. Gileadi",

year = "1984",

month = sep,

doi = "10.1149/1.2116019",

language = "אנגלית",

volume = "131",

pages = "2058--2062",

journal = "Journal of the Electrochemical Society",

issn = "0013-4651",

publisher = "Electrochemical Society, Inc.",

number = "9",

}

TY - JOUR

T1 - Cyclic Voltammetry In Solutions Of Aluminum Bromide And Kbr In Aromatic Hydrocarbons Iii. The Behavior Of Ag And Cu

AU - Elam, M.

AU - Peled, E.

AU - Gileadi, E.

PY - 1984/9

Y1 - 1984/9

N2 - The electrochemical behavior of AgBr and CuBr has been studied in a solution consisting of 0.80M KBr and 1.0M Al2Br6 in ethylbenzene. A significant crystallization overpotential is observed for Cu on Pt, while silver exhibits only a marginally small crystallization overpotential. Measurements of the diffusion coefficients by different methods and comparison with earlier results yield values in the range of (1.1-2.9) x 10-6cm2/s (corresponding to Stokes radii of 9-4Å), except for Cu, which yields a value of (10–21) x 10-6cm2/s. These high apparent values are probably due to catalytic decomposition of the solvent caused by the presence of cuprous ions. The relatively high value for the diffusion coefficient of mercuric ions in toluene reported in an earlier publication is probably due to the same effect.

AB - The electrochemical behavior of AgBr and CuBr has been studied in a solution consisting of 0.80M KBr and 1.0M Al2Br6 in ethylbenzene. A significant crystallization overpotential is observed for Cu on Pt, while silver exhibits only a marginally small crystallization overpotential. Measurements of the diffusion coefficients by different methods and comparison with earlier results yield values in the range of (1.1-2.9) x 10-6cm2/s (corresponding to Stokes radii of 9-4Å), except for Cu, which yields a value of (10–21) x 10-6cm2/s. These high apparent values are probably due to catalytic decomposition of the solvent caused by the presence of cuprous ions. The relatively high value for the diffusion coefficient of mercuric ions in toluene reported in an earlier publication is probably due to the same effect.

UR - http://www.scopus.com/inward/record.url?scp=0021500672&partnerID=8YFLogxK

U2 - 10.1149/1.2116019

DO - 10.1149/1.2116019

M3 - מאמר

AN - SCOPUS:0021500672

VL - 131

SP - 2058

EP - 2062

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

SN - 0013-4651

IS - 9

ER -

Cyclic Voltammetry In Solutions Of Aluminum Bromide And Kbr In Aromatic Hydrocarbons Iii. The Behavior Of Ag And Cu

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this