Crystallographic transitions related to high-pressure magnetic and electronic phenomena in Fe-based compounds

G. Kh Rozenberg, M. P. Pasternak, W. M. Xu, L. S. Dubrovinsky, M. Hanfland

Research output: Contribution to journalArticlepeer-review

Abstract

The main purpose of this paper is to address the issue of crystallographic transitions related to magnetic/electronic phenomena in strongly correlated transition metal (TM) compounds in a regime of very high static density. The experimental tools used were: synchrotron X-ray diffraction, Mossbauer spectroscopy and electrical resistivity. We focus on the following cases: (i) high-spin to low-spin transition which could lead to a significant reduction of the TM ionic radii and therefore even a structural transition; (ii) sluggish structural phase transitions in antiferromagnetic insulators FeI2 and FeCl2 attributed to the onset of a Mott transition; (iii) volume dependence of the orbital term of the moment in FeI2 and FeCl 2 resulting in its eventual collapse, which is accompanied by a significant lattice distortion; and (iv) pressure-induced metal-metal intervalence charge transfer in the antiferromagnetic Cu1+Fe 3+O2 as a result of the increase in overlap of atomic orbitals.

Original languageEnglish
Pages (from-to)238-251
Number of pages14
JournalHigh Pressure Research
Volume30
Issue number2
DOIs
StatePublished - Jun 2010

Keywords

  • Electronic/magnetic transitions
  • High pressure
  • Strongly correlated systems
  • X-ray crystallography

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