Constructing the OCF2O moiety using BrF3

Youlia Hagooly; Shlomo Rozen

doi:10.1021/jo801116n

Constructing the OCF₂O moiety using BrF₃

Youlia Hagooly, Shlomo Rozen^*

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

(Chemical Equation Presented) A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF ₃. The fluorination step is complete in seconds with moderate to high yields under mild conditions.

Original language	English
Pages (from-to)	6780-6783
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	73
Issue number	17
DOIs	https://doi.org/10.1021/jo801116n
State	Published - 5 Sep 2008

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abstract = "(Chemical Equation Presented) A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF 3. The fluorination step is complete in seconds with moderate to high yields under mild conditions.",

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AB - (Chemical Equation Presented) A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF 3. The fluorination step is complete in seconds with moderate to high yields under mild conditions.

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Constructing the OCF₂O moiety using BrF₃

Abstract

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