Confined molecular motion across liquid/liquid interfaces in a triphasic reaction towards free-standing conductive polymer tube arrays

Tuo Ji; Wei Cao; Long Chen; Liwen Mu; Huaiyuan Wang; Xiong Gong; Xiaohua Lu; Jiahua Zhu

doi:10.1039/c6ta01247g

Confined molecular motion across liquid/liquid interfaces in a triphasic reaction towards free-standing conductive polymer tube arrays

Tuo Ji, Wei Cao, Long Chen, Liwen Mu, Huaiyuan Wang, Xiong Gong, Xiaohua Lu, Jiahua Zhu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A "water/oil/water" triphasic reaction system was employed to control diffusion and reaction at separate "water/oil" and "oil/water" interfaces. The former controls the reactant feed rate and the latter determines the reaction rate. By the synergistic integration of diffusion and reaction in one reactor, freestanding tubular-arrayed polymer thin films were successfully fabricated. Molecular dynamics simulation was performed to understand the reactant diffusion across the two interfaces.

Original language	English
Pages (from-to)	6290-6294
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	4
Issue number	17
DOIs	https://doi.org/10.1039/c6ta01247g
State	Published - 2016
Externally published	Yes

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10.1039/c6ta01247g

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AU - Ji, Tuo

AU - Cao, Wei

AU - Chen, Long

AU - Mu, Liwen

AU - Wang, Huaiyuan

AU - Gong, Xiong

AU - Lu, Xiaohua

AU - Zhu, Jiahua

PY - 2016

Y1 - 2016

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AB - A "water/oil/water" triphasic reaction system was employed to control diffusion and reaction at separate "water/oil" and "oil/water" interfaces. The former controls the reactant feed rate and the latter determines the reaction rate. By the synergistic integration of diffusion and reaction in one reactor, freestanding tubular-arrayed polymer thin films were successfully fabricated. Molecular dynamics simulation was performed to understand the reactant diffusion across the two interfaces.

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JO - Journal of Materials Chemistry A

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ER -

Confined molecular motion across liquid/liquid interfaces in a triphasic reaction towards free-standing conductive polymer tube arrays

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