Conducting polymers of tungsten(VI)-oxo calixarene: Intercalation of neutral organic guests

A. Vigalok, T. M. Swager

Research output: Contribution to journalArticlepeer-review

42 Scopus citations

Abstract

Conducting polymers that contain host-guest complex units have been synthesized by electropolymerization of bis-(bithiophene)-substituted tungsten-capped calixarenes (see Figure for general formula). The guest molecule, weakly bonded to the tungsten atom, participates in electron transport. Hence, the conductivity depends on the guest's chemical nature, making the polymer potentially useful as a small-molecule sensor.

Original languageEnglish
Pages (from-to)368-371
Number of pages4
JournalAdvanced Materials
Volume14
Issue number5
DOIs
StatePublished - 4 Mar 2002
Externally publishedYes

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