TY - JOUR
T1 - Concerted coordination and hydrogen-bonding network of the 1,4-di-4-pyridyl-2,3-diaza-1,3-butadiene [Zn(MeOH)2(H 2O)2](ClO4)2 3:1 complex
AU - Shoshnik, Rinat
AU - Elengoz, Helena
AU - Goldberg, Israel
PY - 2005/4
Y1 - 2005/4
N2 - In the title compound, diaquabis(1,4-di-4-pyridyl-2,3-diaza1,3-butadiene) dimethanolzinc(II) bis(perchlorate) 1,4-di-4-pyridyl-2,3-diaza-1,3-butadiene methanol 1.72-solvate 1.28-hydrate, [Zn(C12H10N 4)2(CH4O)2(H2O) 2](ClO4)2·-C12H 10N4·1.72CH4O-1.28H2O, determined at ca 110 K, the Zn cation and the extended dipyridyl ligand both lie across inversion centres in space group P1̄. The structure consists of a network arrangement of the constituent species stabilized by a combination of coordination, hydrogen bonding and π-π forces. Uncoordinated methanol and water solvent molecules occupy the otherwise void spaces within and between the networks.
AB - In the title compound, diaquabis(1,4-di-4-pyridyl-2,3-diaza1,3-butadiene) dimethanolzinc(II) bis(perchlorate) 1,4-di-4-pyridyl-2,3-diaza-1,3-butadiene methanol 1.72-solvate 1.28-hydrate, [Zn(C12H10N 4)2(CH4O)2(H2O) 2](ClO4)2·-C12H 10N4·1.72CH4O-1.28H2O, determined at ca 110 K, the Zn cation and the extended dipyridyl ligand both lie across inversion centres in space group P1̄. The structure consists of a network arrangement of the constituent species stabilized by a combination of coordination, hydrogen bonding and π-π forces. Uncoordinated methanol and water solvent molecules occupy the otherwise void spaces within and between the networks.
UR - http://www.scopus.com/inward/record.url?scp=18544372367&partnerID=8YFLogxK
U2 - 10.1107/S0108270105005329
DO - 10.1107/S0108270105005329
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C2 - 15805617
AN - SCOPUS:18544372367
SN - 0108-2701
VL - 61
SP - m187-m189
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 4
ER -