TY - JOUR
T1 - Chirality induced spin selectivity
T2 - A classical spin-off
AU - Chen, Yun
AU - Hod, Oded
N1 - Publisher Copyright:
© 2023 Author(s).
PY - 2023/6/28
Y1 - 2023/6/28
N2 - We demonstrate that angular momentum selectivity of particles traversing chiral environments is not limited to the quantum regime and can be realized in classical scenarios also. In our classical variant, the electron spin, which is central to the quantum chirality induced spin selectivity (CISS) effect, is replaced by the self-rotation of a finite-volume body. The latter is coupled to the center of mass orbital motion of the body through a helical tube via wall friction that acts as a dissipative spin-orbit coupling term. As a specific example, we study C60 molecules that are initially spinning in opposite senses and investigate the effect of various external control parameters on their spatial separation when driven through a rigid helical channel. We highlight resemblances and inherent differences between the quantum CISS effect and its classical variant and discuss the potential of the latter to formulate a new paradigm for enantio-separation.
AB - We demonstrate that angular momentum selectivity of particles traversing chiral environments is not limited to the quantum regime and can be realized in classical scenarios also. In our classical variant, the electron spin, which is central to the quantum chirality induced spin selectivity (CISS) effect, is replaced by the self-rotation of a finite-volume body. The latter is coupled to the center of mass orbital motion of the body through a helical tube via wall friction that acts as a dissipative spin-orbit coupling term. As a specific example, we study C60 molecules that are initially spinning in opposite senses and investigate the effect of various external control parameters on their spatial separation when driven through a rigid helical channel. We highlight resemblances and inherent differences between the quantum CISS effect and its classical variant and discuss the potential of the latter to formulate a new paradigm for enantio-separation.
UR - http://www.scopus.com/inward/record.url?scp=85163737399&partnerID=8YFLogxK
U2 - 10.1063/5.0156491
DO - 10.1063/5.0156491
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C2 - 37347128
AN - SCOPUS:85163737399
SN - 0021-9606
VL - 158
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
IS - 24
M1 - 244102
ER -