Cathodic electrosynthesis of PZT films

I. Zhitomirsky; A. Kohn; L. Gal-Or

doi:10.1016/0167-577X(95)00191-3

Cathodic electrosynthesis of PZT films

I. Zhitomirsky, A. Kohn, L. Gal-Or

Research output: Contribution to journal › Article › peer-review

Abstract

Cathodic electrosynthesis of lead zirconate titanate (PZT) films on platinum substrates was performed via hydrolysis by electrogenerated base of TiCl4, ZrOCl2 and Pb(NO3)2 salts dissolved in water in the presence of hydrogen peroxide. Possible cathodic reactions which underly the base formation and the role of hydrogen peroxide in the deposition process are discussed. Deposits as-obtained were amorphous and formation of a single perovskite phase was observed after annealing at 500 °C. By variation of current density and deposition time, the amount of the deposited material could be controlled. The films were characterized by XRD, TG/DTA and SEM. © 1995.

Original language	English
Pages (from-to)	223-227
Number of pages	5
Journal	Materials Letters
Volume	25
Issue number	5-6
DOIs	https://doi.org/10.1016/0167-577X(95)00191-3
State	Published - 1995
Externally published	Yes

Keywords

Annealing
Differential thermal analysis
Electrodeposition
Ferroelectric materials
Hydrogen peroxide
Hydrolysis
Perovskite
Platinum
Salts
Semiconducting lead compounds
Substrates
X ray diffraction
Cathodic electrosynthesis
Lead zirconate titanate
Thin films

Access to Document

10.1016/0167-577X(95)00191-3

https://www.scopus.com/inward/record.uri?eid=2-s2.0-0029483758&doi=10.1016%2f0167-577X%2895%2900191-3&partnerID=40&md5=3e2106febe2ef9e491b24cce3684ef98

Cite this

@article{352d86864b1448618238a626260de3e2,

title = "Cathodic electrosynthesis of PZT films",

abstract = "Cathodic electrosynthesis of lead zirconate titanate (PZT) films on platinum substrates was performed via hydrolysis by electrogenerated base of TiCl4, ZrOCl2 and Pb(NO3)2 salts dissolved in water in the presence of hydrogen peroxide. Possible cathodic reactions which underly the base formation and the role of hydrogen peroxide in the deposition process are discussed. Deposits as-obtained were amorphous and formation of a single perovskite phase was observed after annealing at 500 °C. By variation of current density and deposition time, the amount of the deposited material could be controlled. The films were characterized by XRD, TG/DTA and SEM. {\textcopyright} 1995.",

keywords = "Annealing, Differential thermal analysis, Electrodeposition, Ferroelectric materials, Hydrogen peroxide, Hydrolysis, Perovskite, Platinum, Salts, Semiconducting lead compounds, Substrates, X ray diffraction, Cathodic electrosynthesis, Lead zirconate titanate, Thin films",

author = "I. Zhitomirsky and A. Kohn and L. Gal-Or",

note = "cited By 27",

year = "1995",

doi = "10.1016/0167-577X(95)00191-3",

language = "אנגלית",

volume = "25",

pages = "223--227",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier",

number = "5-6",

}

TY - JOUR

T1 - Cathodic electrosynthesis of PZT films

AU - Zhitomirsky, I.

AU - Kohn, A.

AU - Gal-Or, L.

N1 - cited By 27

PY - 1995

Y1 - 1995

N2 - Cathodic electrosynthesis of lead zirconate titanate (PZT) films on platinum substrates was performed via hydrolysis by electrogenerated base of TiCl4, ZrOCl2 and Pb(NO3)2 salts dissolved in water in the presence of hydrogen peroxide. Possible cathodic reactions which underly the base formation and the role of hydrogen peroxide in the deposition process are discussed. Deposits as-obtained were amorphous and formation of a single perovskite phase was observed after annealing at 500 °C. By variation of current density and deposition time, the amount of the deposited material could be controlled. The films were characterized by XRD, TG/DTA and SEM. © 1995.

AB - Cathodic electrosynthesis of lead zirconate titanate (PZT) films on platinum substrates was performed via hydrolysis by electrogenerated base of TiCl4, ZrOCl2 and Pb(NO3)2 salts dissolved in water in the presence of hydrogen peroxide. Possible cathodic reactions which underly the base formation and the role of hydrogen peroxide in the deposition process are discussed. Deposits as-obtained were amorphous and formation of a single perovskite phase was observed after annealing at 500 °C. By variation of current density and deposition time, the amount of the deposited material could be controlled. The films were characterized by XRD, TG/DTA and SEM. © 1995.

KW - Annealing

KW - Differential thermal analysis

KW - Electrodeposition

KW - Ferroelectric materials

KW - Hydrogen peroxide

KW - Hydrolysis

KW - Perovskite

KW - Platinum

KW - Salts

KW - Semiconducting lead compounds

KW - Substrates

KW - X ray diffraction

KW - Cathodic electrosynthesis

KW - Lead zirconate titanate

KW - Thin films

UR - http://www.scopus.com/inward/record.url?scp=0029483758&partnerID=8YFLogxK

U2 - 10.1016/0167-577X(95)00191-3

DO - 10.1016/0167-577X(95)00191-3

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

SN - 0167-577X

VL - 25

SP - 223

EP - 227

JO - Materials Letters

JF - Materials Letters

IS - 5-6

ER -

Cathodic electrosynthesis of PZT films

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this