Carbon-carbon activation by rhodium in solution; sp2-sp 3 is preferred over sp3-sp3 bond cleavage

Shyh Yeon Liou; Michael Gozin; David Milstein

doi:10.1039/C39950001965

Carbon-carbon activation by rhodium in solution; sp²-sp ³ is preferred over sp³-sp³ bond cleavage

Shyh Yeon Liou, Michael Gozin, David Milstein

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of the ethyl-aromatic phosphine 1 with PhRh(PPh₃) ₃ results in C-H activation, yielding complex 2, which upon treatment with H₂ undergoes selective cleavage of the sp²-sp ³ hybridized C-C bond forming ethane and complex 3; Ar-C cleavage is also observed upon reaction of 1 with H₂ and [RhCl(C ₈H₁₄)₂]₂.

Original language	English
Pages (from-to)	1965-1966
Number of pages	2
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39950001965
State	Published - 1995
Externally published	Yes

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title = "Carbon-carbon activation by rhodium in solution; sp2-sp 3 is preferred over sp3-sp3 bond cleavage",

abstract = "Reaction of the ethyl-aromatic phosphine 1 with PhRh(PPh3) 3 results in C-H activation, yielding complex 2, which upon treatment with H2 undergoes selective cleavage of the sp2-sp 3 hybridized C-C bond forming ethane and complex 3; Ar-C cleavage is also observed upon reaction of 1 with H2 and [RhCl(C 8H14)2]2.",

author = "Liou, {Shyh Yeon} and Michael Gozin and David Milstein",

year = "1995",

doi = "10.1039/C39950001965",

language = "אנגלית",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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AU - Milstein, David

PY - 1995

Y1 - 1995

N2 - Reaction of the ethyl-aromatic phosphine 1 with PhRh(PPh3) 3 results in C-H activation, yielding complex 2, which upon treatment with H2 undergoes selective cleavage of the sp2-sp 3 hybridized C-C bond forming ethane and complex 3; Ar-C cleavage is also observed upon reaction of 1 with H2 and [RhCl(C 8H14)2]2.

AB - Reaction of the ethyl-aromatic phosphine 1 with PhRh(PPh3) 3 results in C-H activation, yielding complex 2, which upon treatment with H2 undergoes selective cleavage of the sp2-sp 3 hybridized C-C bond forming ethane and complex 3; Ar-C cleavage is also observed upon reaction of 1 with H2 and [RhCl(C 8H14)2]2.

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JO - Chemical Communications

JF - Chemical Communications

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Carbon-carbon activation by rhodium in solution; sp²-sp ³ is preferred over sp³-sp³ bond cleavage

Abstract

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