TY - JOUR
T1 - Capillary waves at soft electrified interfaces
AU - Daikhin, L. I.
AU - Kornyshev, A. A.
AU - Urbakh, M.
N1 - Funding Information:
The authors are grateful to Ilan Benjamin, Bob Samec and Sasha Volkov for useful discussions and consultations. The financial support of this work by DAAD and the Bureau of Public Relations, International and Industrial Affairs of the Research Center Juelich is greatly appreciated.
PY - 2000/3/30
Y1 - 2000/3/30
N2 - Recent theory of capillary waves along the interface between two immiscible electrolytes is generalized to include the non-linear polarization of the double layer. The theory covers both the effects of the capillary waves on the double layer capacitance, as well as the effect of charging the interface on the amplitudes and spectrum of capillary waves. The theory explains major available experimental data, such as the interfacial capacitance dependence on the potential drop across the interface and on ionic strength. It also predicts a number of new effects, such as the influence of electric field and electrolyte concentration on the surface corrugation correlation function, and in particular, on the mean square height of corrugation.
AB - Recent theory of capillary waves along the interface between two immiscible electrolytes is generalized to include the non-linear polarization of the double layer. The theory covers both the effects of the capillary waves on the double layer capacitance, as well as the effect of charging the interface on the amplitudes and spectrum of capillary waves. The theory explains major available experimental data, such as the interfacial capacitance dependence on the potential drop across the interface and on ionic strength. It also predicts a number of new effects, such as the influence of electric field and electrolyte concentration on the surface corrugation correlation function, and in particular, on the mean square height of corrugation.
UR - http://www.scopus.com/inward/record.url?scp=0033872937&partnerID=8YFLogxK
U2 - 10.1016/S0022-0728(00)00054-1
DO - 10.1016/S0022-0728(00)00054-1
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AN - SCOPUS:0033872937
SN - 0022-0728
VL - 483
SP - 68
EP - 80
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
IS - 1
T2 - The Euroconference on Modern Trends in Electrochemistry of Molecular Interfaces
Y2 - 28 August 1999 through 3 September 1999
ER -