Calculation of outer Helmholtz potential at mercury as a function of temperature and concentration of aqueous sodium fluoride solutions

E. Kirowa-Eisner; D. Tzur; M. Schwarz

doi:10.1016/0022-0728(94)03492-L

Calculation of outer Helmholtz potential at mercury as a function of temperature and concentration of aqueous sodium fluoride solutions

E. Kirowa-Eisner^*, D. Tzur, M. Schwarz

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Potentials of the outer Helmholtz plane, ø₂, at mercury as function of electrode potential and temperature are calculated on the basis of the Gouy-Chapman theory using Grahame's data for surface charge and capacitance in aqueous NaF solutions. An empirical equation for calculating ø₂ at negative rational potential is presented. Grahame's original data of surface charge and capacitance are summarized in ASCII files on floppy disk.

Original language	English
Pages (from-to)	11-14
Number of pages	4
Journal	Journal of Electroanalytical Chemistry
Volume	381
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-0728(94)03492-L
State	Published - 24 Jan 1995

Keywords

Mercury electrode
Outer helmholtz potential
Sodium fluoride

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10.1016/0022-0728(94)03492-L

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abstract = "Potentials of the outer Helmholtz plane, {\o}2, at mercury as function of electrode potential and temperature are calculated on the basis of the Gouy-Chapman theory using Grahame's data for surface charge and capacitance in aqueous NaF solutions. An empirical equation for calculating {\o}2 at negative rational potential is presented. Grahame's original data of surface charge and capacitance are summarized in ASCII files on floppy disk.",

keywords = "Mercury electrode, Outer helmholtz potential, Sodium fluoride",

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AU - Kirowa-Eisner, E.

AU - Tzur, D.

AU - Schwarz, M.

PY - 1995/1/24

Y1 - 1995/1/24

N2 - Potentials of the outer Helmholtz plane, ø2, at mercury as function of electrode potential and temperature are calculated on the basis of the Gouy-Chapman theory using Grahame's data for surface charge and capacitance in aqueous NaF solutions. An empirical equation for calculating ø2 at negative rational potential is presented. Grahame's original data of surface charge and capacitance are summarized in ASCII files on floppy disk.

AB - Potentials of the outer Helmholtz plane, ø2, at mercury as function of electrode potential and temperature are calculated on the basis of the Gouy-Chapman theory using Grahame's data for surface charge and capacitance in aqueous NaF solutions. An empirical equation for calculating ø2 at negative rational potential is presented. Grahame's original data of surface charge and capacitance are summarized in ASCII files on floppy disk.

KW - Mercury electrode

KW - Outer helmholtz potential

KW - Sodium fluoride

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ER -

Calculation of outer Helmholtz potential at mercury as a function of temperature and concentration of aqueous sodium fluoride solutions

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Keywords

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