@article{f5316a0e8bc3404e9fcc0959f986c8e8,
title = "Block–Stereoblock Copolymers of Poly(ϵ-Caprolactone) and Poly(Lactic Acid)",
abstract = "A magnesium complex of the type \{ONNN\}Mg-HMDS wherein \{ONNN\} is a sequential tetradentate monoanionic ligand is introduced. In the presence of an alcohol initiator this complex catalyzes the living and immortal homopolymerization of the lactide enantiomers and ϵ-caprolactone at room-temperature with exceptionally high activities, as well as the precise block copolymerization of these monomers in a one-pot synthesis by sequential monomer addition. Copolymers of unprecedented microstructures such as the PCL-b-PLLA-b-PDLA and PDLA-b-PLLA-b-PCL-b-PLLA-b-PDLA block–stereoblock microstructures that feature unique thermal properties are readily accessed.",
keywords = "block copolymers, living polymerization, magnesium, poly(lactic acid), poly(ϵ-caprolactone)",
author = "Tomer Rosen and Israel Goldberg and Wanda Navarra and Vincenzo Venditto and Moshe Kol",
note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",
year = "2018",
month = jun,
day = "11",
doi = "10.1002/anie.201803063",
language = "אנגלית",
volume = "57",
pages = "7191--7195",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "24",
}