@article{b9f71f902e0e4381b7b9e832dad9de67,
title = "Bis(aniline-phenolate) complexes of group 4 metals: Coordination chemistry and lactide polymerization catalysis",
abstract = "The substituted aniline-phenol ligand binds in the reduced-monoanionic form to the group 4 metals giving fluxional octahedral [\{NO\}2M(OR) 2]-type complexes. The X-ray structures of the Zr- and Hf-complexes revealed cis-N/trans-O binding and an overall C1 symmetry. All three complexes exhibited high activities in polymerization of L-lactide and rac-lactide. The Zr- and Hf-complexes led to heterotactically enriched PLA.",
keywords = "Group 4 complexes, N,O-ligands, Poly(lactic acid), Polymerization",
author = "Ayellet Stopper and Israel Goldberg and Moshe Kol",
note = "Funding Information: We thank the Israel Science Foundation and the United States–Israel Binational Science Foundation for financial support. ",
year = "2011",
month = may,
doi = "10.1016/j.inoche.2011.02.014",
language = "אנגלית",
volume = "14",
pages = "715--718",
journal = "Inorganic Chemistry Communications",
issn = "1387-7003",
publisher = "Elsevier B.V.",
number = "5",
}