Attraction controls the entropy of fluctuations in isosceles triangular networks

Fabio Leoni, Yair Shokef*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

We study two-dimensional triangular-network models, which have degenerate ground states composed of straight or randomly-zigzagging stripes and thus sub-extensive residual entropy. We show that attraction is responsible for the inversion of the stable phase by changing the entropy of fluctuations around the ground-state configurations. By using a real-space shell-expansion method, we compute the exact expression of the entropy for harmonic interactions, while for repulsive harmonic interactions we obtain the entropy arising from a limited subset of the system by numerical integration. We compare these results with a three-dimensional triangular-network model, which shows the same attraction-mediated selection mechanism of the stable phase, and conclude that this effect is general with respect to the dimensionality of the system.

Original languageEnglish
Article number122
JournalEntropy
Volume20
Issue number2
DOIs
StatePublished - 1 Feb 2018

Keywords

  • Confined colloids
  • Geometric frustration
  • Order by disorder
  • Residual entropy

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