Aryl-halide versus aryl-aryl reductive elimination in Pt(IV)-phosphine complexes

Anette Yahav-Levi, Israel Goldberg, Arkadi Vigalok

Research output: Contribution to journalArticlepeer-review

Abstract

Upon the addition of Br2 to complexes (P-P)Pt(Ar)2, two different products were observed, depending on the bite angle of the bidentate phosphine ligand: a Pt(II) aryl bromide complex, the product of C-Br reductive elimination, and Pt(IV) oxidative addition complex. At high temperatures, the latter exclusively gave the product of the C-C reductive elimination.

Original languageEnglish
Pages (from-to)8710-8711
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number27
DOIs
StatePublished - 12 Jul 2006

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