Aryl-halide versus aryl-aryl reductive elimination in Pt(IV)-phosphine complexes

Anette Yahav-Levi; Israel Goldberg; Arkadi Vigalok

doi:10.1021/ja062166r

Aryl-halide versus aryl-aryl reductive elimination in Pt(IV)-phosphine complexes

Anette Yahav-Levi, Israel Goldberg, Arkadi Vigalok^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Upon the addition of Br₂ to complexes (P-P)Pt(Ar)₂, two different products were observed, depending on the bite angle of the bidentate phosphine ligand: a Pt(II) aryl bromide complex, the product of C-Br reductive elimination, and Pt(IV) oxidative addition complex. At high temperatures, the latter exclusively gave the product of the C-C reductive elimination.

Original language	English
Pages (from-to)	8710-8711
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	27
DOIs	https://doi.org/10.1021/ja062166r
State	Published - 12 Jul 2006

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title = "Aryl-halide versus aryl-aryl reductive elimination in Pt(IV)-phosphine complexes",

abstract = "Upon the addition of Br2 to complexes (P-P)Pt(Ar)2, two different products were observed, depending on the bite angle of the bidentate phosphine ligand: a Pt(II) aryl bromide complex, the product of C-Br reductive elimination, and Pt(IV) oxidative addition complex. At high temperatures, the latter exclusively gave the product of the C-C reductive elimination.",

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AB - Upon the addition of Br2 to complexes (P-P)Pt(Ar)2, two different products were observed, depending on the bite angle of the bidentate phosphine ligand: a Pt(II) aryl bromide complex, the product of C-Br reductive elimination, and Pt(IV) oxidative addition complex. At high temperatures, the latter exclusively gave the product of the C-C reductive elimination.

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Aryl-halide versus aryl-aryl reductive elimination in Pt(IV)-phosphine complexes

Abstract

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