Aryl-F Bond Cleavage vs. C-E Reductive Elimination: Competitive Pathways of Metal-Ligand-Cooperation-Based E-H Bond Activation (E = N, S)

Keyphrases

• Hydrogen Bonds (H-bonds) 100%
• Amides 100%
• Aryl 100%
• Reductive Elimination 100%
• Metal-ligand Cooperation 100%
• Bond Activation 100%
• Bond Cleavage 100%
• Competitive Pathway 100%
• Cooperation-based 100%
• Cooperation Mechanism 66%
• Sulfide 33%
• Fluoroquinolones 33%
• Activation Energy 33%
• DFT Study 33%
• DFT Calculations 33%
• Reaction Pathway 33%
• Thiophenol 33%
• Pincer Complexes 33%
• Pd(II) Complexes 33%
• Low Activation Barrier 33%
• Fluorine Atom 33%
• Coupling Reaction 33%
• Pincer 33%
• Coupling Products 33%
• Hydrogen Atom Transfer 33%
• Intramolecular nucleophilic Substitution 33%
• N-methylaniline 33%
• Aromatic nucleophilic Substitution 33%

Chemistry

• Carboxamide 100%
• Reductive Elimination Reaction 100%
• Density Functional Theory 33%
• Hydrogen Atom 33%
• Coupling Reaction 33%
• Fluorine 33%
• Thiophenol 33%
• Pincer Complex 33%
• Reaction Activation Energy 33%
• Sulfide 33%
• Fluorine Atom 33%
• N-Methylaniline 33%
• Nucleophilic Aromatic Substitution 33%
• formation 33%
• Density Functional Theory 33%
• Nucleophilic Substitution 33%