Abstract
We consider a simple model, the two-site small-polaron system, and show that its properties can be characterized by a master equation which is in accordance with recent quantum statistical theories of macroscopic observables. It is shown by a combination of formal and numerical analyses that the model is an example of a system describable by the lowest-order term in the expansion of the kernel of the master equation in powers of the ratio of the average polaron-phonon interaction energy to the microscopic phonon energy. We discuss the relevance of the method to actual physical systems.
Original language | English |
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Pages (from-to) | 361-371 |
Number of pages | 11 |
Journal | Journal of Statistical Physics |
Volume | 7 |
Issue number | 4 |
DOIs | |
State | Published - Apr 1973 |
Keywords
- Transport
- macrostate
- master equation
- small polarons
- small-parameter expansion