Absorption Spectra of Nitric Oxide in Solutions

Raphael Grajower; Joshua Jortner

doi:10.1021/ja00888a005

Absorption Spectra of Nitric Oxide in Solutions

Raphael Grajower, Joshua Jortner

Hebrew University of Jerusalem

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The absorption spectra of nitric oxide in aromatic and aliphatic hydrocarbons, in alcohols and in water were investigated. The experimental results show that the broad structureless absorption bands observed rise from charge transfer between the solvent and NO. Thermochemical data indicate that the solvent-NO interactions are due to contacts in solution without the formation of a stable complex. The charge transfer spectra of NO and O₂ solution are compared. The enhancement of singlet-triplet transitions of benzene and the quenching mechanism of triplet states by NO are considered briefly.

Original language	English
Pages (from-to)	512-516
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	85
Issue number	5
DOIs	https://doi.org/10.1021/ja00888a005
State	Published - 1 Mar 1963
Externally published	Yes

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abstract = "The absorption spectra of nitric oxide in aromatic and aliphatic hydrocarbons, in alcohols and in water were investigated. The experimental results show that the broad structureless absorption bands observed rise from charge transfer between the solvent and NO. Thermochemical data indicate that the solvent-NO interactions are due to contacts in solution without the formation of a stable complex. The charge transfer spectra of NO and O2 solution are compared. The enhancement of singlet-triplet transitions of benzene and the quenching mechanism of triplet states by NO are considered briefly.",

author = "Raphael Grajower and Joshua Jortner",

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N2 - The absorption spectra of nitric oxide in aromatic and aliphatic hydrocarbons, in alcohols and in water were investigated. The experimental results show that the broad structureless absorption bands observed rise from charge transfer between the solvent and NO. Thermochemical data indicate that the solvent-NO interactions are due to contacts in solution without the formation of a stable complex. The charge transfer spectra of NO and O2 solution are compared. The enhancement of singlet-triplet transitions of benzene and the quenching mechanism of triplet states by NO are considered briefly.

AB - The absorption spectra of nitric oxide in aromatic and aliphatic hydrocarbons, in alcohols and in water were investigated. The experimental results show that the broad structureless absorption bands observed rise from charge transfer between the solvent and NO. Thermochemical data indicate that the solvent-NO interactions are due to contacts in solution without the formation of a stable complex. The charge transfer spectra of NO and O2 solution are compared. The enhancement of singlet-triplet transitions of benzene and the quenching mechanism of triplet states by NO are considered briefly.

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Absorption Spectra of Nitric Oxide in Solutions

Abstract

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