A thermally switchable latent ruthenium olefin metathesis catalyst

Amos Ben-Asuly; Eyal Tzur; Charles E. Diesendruck; Mark Sigalov; Israel Goldberg; N. Gabriel Lemcoff

doi:10.1021/om701180z

A thermally switchable latent ruthenium olefin metathesis catalyst

Amos Ben-Asuly, Eyal Tzur, Charles E. Diesendruck, Mark Sigalov, Israel Goldberg, N. Gabriel Lemcoff

School of Chemistry

Research output: Contribution to journal › Article › peer-review

149 Scopus citations

Abstract

The synthesis and characterization of a cis-dichloro sulfur chelated olefin metathesis catalyst is presented. The catalyst was extremely stable at room temperature in solution under ambient conditions and was shown to exhibit a thermoswitchable behavior for ring-closing olefin metathesis of diethyl diallylmalonate, being active at 80°C and inactive at room temperature.

Original language	English
Pages (from-to)	811-813
Number of pages	3
Journal	Organometallics
Volume	27
Issue number	5
DOIs	https://doi.org/10.1021/om701180z
State	Published - 10 Mar 2008

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10.1021/om701180z

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title = "A thermally switchable latent ruthenium olefin metathesis catalyst",

abstract = "The synthesis and characterization of a cis-dichloro sulfur chelated olefin metathesis catalyst is presented. The catalyst was extremely stable at room temperature in solution under ambient conditions and was shown to exhibit a thermoswitchable behavior for ring-closing olefin metathesis of diethyl diallylmalonate, being active at 80°C and inactive at room temperature.",

author = "Amos Ben-Asuly and Eyal Tzur and Diesendruck, {Charles E.} and Mark Sigalov and Israel Goldberg and Lemcoff, {N. Gabriel}",

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doi = "10.1021/om701180z",

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AU - Ben-Asuly, Amos

AU - Tzur, Eyal

AU - Diesendruck, Charles E.

AU - Sigalov, Mark

AU - Goldberg, Israel

AU - Lemcoff, N. Gabriel

PY - 2008/3/10

Y1 - 2008/3/10

N2 - The synthesis and characterization of a cis-dichloro sulfur chelated olefin metathesis catalyst is presented. The catalyst was extremely stable at room temperature in solution under ambient conditions and was shown to exhibit a thermoswitchable behavior for ring-closing olefin metathesis of diethyl diallylmalonate, being active at 80°C and inactive at room temperature.

AB - The synthesis and characterization of a cis-dichloro sulfur chelated olefin metathesis catalyst is presented. The catalyst was extremely stable at room temperature in solution under ambient conditions and was shown to exhibit a thermoswitchable behavior for ring-closing olefin metathesis of diethyl diallylmalonate, being active at 80°C and inactive at room temperature.

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A thermally switchable latent ruthenium olefin metathesis catalyst

Abstract

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