A self-catalyzed reaction of 1,2-dibenzoyl-: O-carborane with hydrosilanes-formation of new hydrofuranes

Kuldeep Jaiswal, Solomon Volodarsky, Vladimir Kampel, Roman Dobrovetsky*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The activation of Si-H bonds is a very important transformation both in organic and inorganic chemistry. Herein we report that 1,2-dibenzoyl-o-carborane (1) reacts with Si-H bonds, yielding new hydrofurane-type products. The mechanism of this Si-H bond activation was studied both experimentally and by DFT calculations, and supposedly proceeds in an FLP-type manner.

Original languageEnglish
Pages (from-to)10448-10451
Number of pages4
JournalChemical Communications
Volume55
Issue number70
DOIs
StatePublished - 2019

Funding

FundersFunder number
Israel Ministry of Science Technology & Space65692
Israeli Science Foundation237/18

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