A novel synthesis of trifluoromethyl ethers via xanthates, utilizing BrF3

Iris Ben-David; Dalit Rechavi; Eyal Mishani; Shlomo Rozen

doi:10.1016/S0022-1139(99)00031-7

A novel synthesis of trifluoromethyl ethers via xanthates, utilizing BrF₃

Iris Ben-David, Dalit Rechavi, Eyal Mishani, Shlomo Rozen

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Alcohols were transformed into trifluoromethyl ethers by converting them to xanthates in almost quantitative yields followed by a reaction with bromine trifluoride, a reagent rarely used in organic chemistry.

Original language	English
Pages (from-to)	75-78
Number of pages	4
Journal	Journal of Fluorine Chemistry
Volume	97
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-1139(99)00031-7
State	Published - 20 Jul 1999

Keywords

Alcohols to trifluoromethoxy
Bromine trifluoride
Trifluoromethyl ethers

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10.1016/S0022-1139(99)00031-7

Cite this

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title = "A novel synthesis of trifluoromethyl ethers via xanthates, utilizing BrF3",

abstract = "Alcohols were transformed into trifluoromethyl ethers by converting them to xanthates in almost quantitative yields followed by a reaction with bromine trifluoride, a reagent rarely used in organic chemistry.",

keywords = "Alcohols to trifluoromethoxy, Bromine trifluoride, Trifluoromethyl ethers",

author = "Iris Ben-David and Dalit Rechavi and Eyal Mishani and Shlomo Rozen",

note = "Funding Information: This research was supported by the USA–Israel Binational Science Foundation (BSF), Jerusalem, Israel. ",

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AU - Ben-David, Iris

AU - Rechavi, Dalit

AU - Mishani, Eyal

AU - Rozen, Shlomo

N1 - Funding Information: This research was supported by the USA–Israel Binational Science Foundation (BSF), Jerusalem, Israel.

PY - 1999/7/20

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N2 - Alcohols were transformed into trifluoromethyl ethers by converting them to xanthates in almost quantitative yields followed by a reaction with bromine trifluoride, a reagent rarely used in organic chemistry.

AB - Alcohols were transformed into trifluoromethyl ethers by converting them to xanthates in almost quantitative yields followed by a reaction with bromine trifluoride, a reagent rarely used in organic chemistry.

KW - Alcohols to trifluoromethoxy

KW - Bromine trifluoride

KW - Trifluoromethyl ethers

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A novel synthesis of trifluoromethyl ethers via xanthates, utilizing BrF₃

Abstract

Keywords

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