A novel energetic material based on nitro-nno-azoxy: synthesis and characterization

Hui Li; Feng Qi Zhao; Qian Qian Yu; Wei Peng Lai; Bo Zhou Wang

doi:10.11943/j.issn.1006-9941.2014.06.032

A novel energetic material based on nitro-nno-azoxy: synthesis and characterization

Hui Li, Feng Qi Zhao, Qian Qian Yu, Wei Peng Lai, Bo Zhou Wang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A novel energetic compound, N, N'-dinitro-N, N'-bis [3- (nitro-NNO-azoxy)furazan-4-yl] methylenediamine, was synthesized using 3-amino-4- (t-Bu-NNO-azoxy)furazan as starting material. And its structure was characterized by nuclear magnetic resonance (¹H NMR and ¹³C NMR), infrared (IR) spectroscopy, elemental analysis and mass spectrometry, and its backbone was also confirmed by the X-ray structure study of the key intermediate. The detonation performance was calculated by VLW equation of state. Results show density is 1.94 g·cm^-3, detonation velocity 9502.52 m·s^-1, detonation pressure 41.79 GPa and enthalpy of formation 1007.67 kJ·mol^-1, indicating it is a competitive energetic materials.

Original language	English
Pages (from-to)	880-883
Number of pages	4
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	22
Issue number	6
DOIs	https://doi.org/10.11943/j.issn.1006-9941.2014.06.032
State	Published - 25 Dec 2014
Externally published	Yes

Keywords

Design
Energetic materials
Nitro-NNO-azoxy
Organic chemistry
Performance
Synthesis

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10.11943/j.issn.1006-9941.2014.06.032

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title = "A novel energetic material based on nitro-nno-azoxy: synthesis and characterization",

abstract = "A novel energetic compound, N, N'-dinitro-N, N'-bis [3- (nitro-NNO-azoxy)furazan-4-yl] methylenediamine, was synthesized using 3-amino-4- (t-Bu-NNO-azoxy)furazan as starting material. And its structure was characterized by nuclear magnetic resonance (1H NMR and 13C NMR), infrared (IR) spectroscopy, elemental analysis and mass spectrometry, and its backbone was also confirmed by the X-ray structure study of the key intermediate. The detonation performance was calculated by VLW equation of state. Results show density is 1.94 g·cm-3, detonation velocity 9502.52 m·s-1, detonation pressure 41.79 GPa and enthalpy of formation 1007.67 kJ·mol-1, indicating it is a competitive energetic materials.",

keywords = "Design, Energetic materials, Nitro-NNO-azoxy, Organic chemistry, Performance, Synthesis",

author = "Hui Li and Zhao, {Feng Qi} and Yu, {Qian Qian} and Lai, {Wei Peng} and Wang, {Bo Zhou}",

year = "2014",

month = dec,

day = "25",

doi = "10.11943/j.issn.1006-9941.2014.06.032",

language = "אנגלית",

volume = "22",

pages = "880--883",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Chinese Academy of Engineering Physics",

number = "6",

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T1 - A novel energetic material based on nitro-nno-azoxy

T2 - synthesis and characterization

AU - Li, Hui

AU - Zhao, Feng Qi

AU - Yu, Qian Qian

AU - Lai, Wei Peng

AU - Wang, Bo Zhou

PY - 2014/12/25

Y1 - 2014/12/25

N2 - A novel energetic compound, N, N'-dinitro-N, N'-bis [3- (nitro-NNO-azoxy)furazan-4-yl] methylenediamine, was synthesized using 3-amino-4- (t-Bu-NNO-azoxy)furazan as starting material. And its structure was characterized by nuclear magnetic resonance (1H NMR and 13C NMR), infrared (IR) spectroscopy, elemental analysis and mass spectrometry, and its backbone was also confirmed by the X-ray structure study of the key intermediate. The detonation performance was calculated by VLW equation of state. Results show density is 1.94 g·cm-3, detonation velocity 9502.52 m·s-1, detonation pressure 41.79 GPa and enthalpy of formation 1007.67 kJ·mol-1, indicating it is a competitive energetic materials.

AB - A novel energetic compound, N, N'-dinitro-N, N'-bis [3- (nitro-NNO-azoxy)furazan-4-yl] methylenediamine, was synthesized using 3-amino-4- (t-Bu-NNO-azoxy)furazan as starting material. And its structure was characterized by nuclear magnetic resonance (1H NMR and 13C NMR), infrared (IR) spectroscopy, elemental analysis and mass spectrometry, and its backbone was also confirmed by the X-ray structure study of the key intermediate. The detonation performance was calculated by VLW equation of state. Results show density is 1.94 g·cm-3, detonation velocity 9502.52 m·s-1, detonation pressure 41.79 GPa and enthalpy of formation 1007.67 kJ·mol-1, indicating it is a competitive energetic materials.

KW - Design

KW - Energetic materials

KW - Nitro-NNO-azoxy

KW - Organic chemistry

KW - Performance

KW - Synthesis

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JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 6

ER -

A novel energetic material based on nitro-nno-azoxy: synthesis and characterization

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Keywords

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