A novel diaminoborate ligand system derived from 1,8-diaminonaphthalene and 9-BBN: Preparation of titanium and zirconium complexes and crystal structure of the titanium complex

Galia Bar-Haim; Romem Shach; Moshe Kol

doi:10.1039/a607194e

A novel diaminoborate ligand system derived from 1,8-diaminonaphthalene and 9-BBN: Preparation of titanium and zirconium complexes and crystal structure of the titanium complex

Galia Bar-Haim, Romem Shach, Moshe Kol^*

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

1,8-Diaminonaphthalene reacts selectively with 1 equiv. of 9-BBN to form a bridging amine-aminoborane, and with 2 equiv. of 9-BBN to form a non-bridging bis(aminoborane); these aminoboranes give rise to a novel diaminoborate (4e,1-) ligand system by reactions with dimethylamides of titanium and zirconium.

Original language	English
Pages (from-to)	229-230
Number of pages	2
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/a607194e
State	Published - 1997

Access to Document

10.1039/a607194e

Cite this

@article{6c7afb38ebdc409dbe1bec9f43eaf2a2,

title = "A novel diaminoborate ligand system derived from 1,8-diaminonaphthalene and 9-BBN: Preparation of titanium and zirconium complexes and crystal structure of the titanium complex",

abstract = "1,8-Diaminonaphthalene reacts selectively with 1 equiv. of 9-BBN to form a bridging amine-aminoborane, and with 2 equiv. of 9-BBN to form a non-bridging bis(aminoborane); these aminoboranes give rise to a novel diaminoborate (4e,1-) ligand system by reactions with dimethylamides of titanium and zirconium.",

author = "Galia Bar-Haim and Romem Shach and Moshe Kol",

year = "1997",

doi = "10.1039/a607194e",

language = "אנגלית",

pages = "229--230",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - A novel diaminoborate ligand system derived from 1,8-diaminonaphthalene and 9-BBN

T2 - Preparation of titanium and zirconium complexes and crystal structure of the titanium complex

AU - Bar-Haim, Galia

AU - Shach, Romem

AU - Kol, Moshe

PY - 1997

Y1 - 1997

N2 - 1,8-Diaminonaphthalene reacts selectively with 1 equiv. of 9-BBN to form a bridging amine-aminoborane, and with 2 equiv. of 9-BBN to form a non-bridging bis(aminoborane); these aminoboranes give rise to a novel diaminoborate (4e,1-) ligand system by reactions with dimethylamides of titanium and zirconium.

AB - 1,8-Diaminonaphthalene reacts selectively with 1 equiv. of 9-BBN to form a bridging amine-aminoborane, and with 2 equiv. of 9-BBN to form a non-bridging bis(aminoborane); these aminoboranes give rise to a novel diaminoborate (4e,1-) ligand system by reactions with dimethylamides of titanium and zirconium.

UR - http://www.scopus.com/inward/record.url?scp=0002249865&partnerID=8YFLogxK

U2 - 10.1039/a607194e

DO - 10.1039/a607194e

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0002249865

SN - 1359-7345

SP - 229

EP - 230

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

A novel diaminoborate ligand system derived from 1,8-diaminonaphthalene and 9-BBN: Preparation of titanium and zirconium complexes and crystal structure of the titanium complex

Abstract

Access to Document

Other files and links

Fingerprint

Cite this