A new method for making acyl fluorides using BrF3

Or Cohen, Revital Sasson, Shlomo Rozen

Research output: Contribution to journalArticlepeer-review

Abstract

While many carboxylic acids could be converted directly to acyl fluorides by using BrF3, the reaction with acyl chlorides was found to be of a more general nature and yields better results. Surprisingly, reacting t-butyl esters with bromine trifluoride also resulted in acyl fluorides in reasonable yields. The reactions were completed in a few seconds at 0°C.

Original languageEnglish
Pages (from-to)433-436
Number of pages4
JournalJournal of Fluorine Chemistry
Volume127
Issue number3
DOIs
StatePublished - Mar 2006

Keywords

  • Acyl fluorides
  • Bromine trifluoride

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