A dimethyl sulfoxide/chloroform clathrate of (dimethyl sulfoxide) (tetraphenylporphyrinato)-zinc(II)

Mikki Vinodu, Israel Goldberg

Research output: Contribution to journalArticlepeer-review

Abstract

The title compound, [Zn(C44H28N4)(C 2H6OS)]·0.79C2H6OS·-0. 21CHCl3, crystallizes as a sulfoxide-chloroform true clath-rate. The main residue, (dimethyl sulfoxide)(tetraphenyl-porphyrinato)zinc(II), is a five-coordinate zinc-porphyrin complex, with dimethyl sulfoxide as an axial ligand. The crystal structure is characterized by a typical layered organization of the porphyrin species, with the solvent guest molecules intercalated between the layers.

Original languageEnglish
Pages (from-to)m579-m581
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number5
DOIs
StatePublished - May 2004

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