A better-developed soil profile during biblical times in the western Galilee. 15 N evidence in 14 C - Dated groundwater

V. Rogojin, J. Kronfeld, Israel Carmi, A. S. Talma

Research output: Contribution to journalArticlepeer-review

Abstract

Despite almost a hundred years of reforestation efforts, the recharge area of the Judea Group aquifer in the hills of the western Galilee still shows the signs of the severe soil erosion that transpired in previous centuries. At present the soil profile is thin and basement rock is often exposed. Historical and Biblical sources suggest that the hills in the past were more forested. Therefore, the 15 N values of dissolved nitrate were measured in radiocarbon-dated groundwater to see if evidence for past soil conditions could be deduced. Nitrate mineralization processes in soils lead to enrichment in 15 N of the residual nitrate, which being dissolved by rain enters into the groundwater without further isotopic fractionation. Previous studies have shown that there is a trend of increasing 15 N in a soil profile from plant, to litter, to the organic material in the soil. In addition, there is a tendency for higher 15 N values to be observed in those samples that have been taken at greater depth in a soil profile due to progressive mineralization and subsequent nitrification of soil organic material. As long as the dissolved oxygen is not depleted, denitrification will not occur to alter the isotopic composition of the dissolved nitrate. The nitrate concentrations and 15 N values, water chemistry, tritium and radiocarbon activities were measured from the phreatic outcrop recharge region, and onwards into the confined portions of the Judea Group aquifer and its continuation into the juxtaposed Kurdani and Pleistocene aquifers. The radiocarbon activity decreases with flow. Tritium values of above 2 TU are restricted to the recharge region. Using an initial 14 C activity of 64 pMC the radiocarbon ages of the water are found to range from recent to 7800 BP. The 15 N values of the dissolved nitrate within the young water recharge area fall in the range of +3.1 to +4.8% (Air), having a mean of +3.9% (n=5). In older water the nitrate concentration increases slightly, while the 15 N ranges from +4.7 to +7.2% (Air), having a mean of +6.4% (n=17). The increase in the 15 N values in the older water down-dip is not due to denitrification processes; for, the waters are well oxygenated. These older waters infiltrated at the same point of origin in the phreatic portions of the aquifer (non-contaminated) as the recent water. As the earlier infiltrating water flowed down dip they retained the 15 N values of the environment at that time. The 15 N values present evidence that, compared to the present, the soil and plant cover was better developed in earlier times, including Biblical times.

Original languageEnglish
Pages (from-to)79-84
Number of pages6
JournalGeochronometria
Volume21
StatePublished - 2002

Keywords

  • Carbon Isotopes
  • Climate changes
  • Landscape changes
  • Nitrogen Isotopes
  • Soil

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