[5,10,15,20-Tetrakis(4-pyridyl)porphy rinato]zinc(II) acetic acid clathrate, and its unique polymeric honeycomb architecture

Sumod George, Israel Goldberg

Research output: Contribution to journalArticlepeer-review

Abstract

The crystal structure of the title compound, [Zn-(C40H 24N8)]·1.6C2H4O2 has been determined at ca 110 K. The centrosymmetric metalloporphyrin compound forms a self-assembled honeycomb architecture, with open channels extending parallel to the c axis of the unit cell. The compound crystallizes as an acetic acid clathrate. The guest species, which are included in the interporphyrin channels, hydrogen bond to the porphyrin framework.

Original languageEnglish
Pages (from-to)m1441-m1443
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number8
DOIs
StatePublished - 1 Aug 2005

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